This is an article from Jim Schulman about espresso extraction, lengthy but great read.
Excerpt from the Intruduction:
Some aromas that promise joy from a brewed cup of coffee elicit dread when smelled in a shot of espresso. Why do so many great brewed coffees taste awful as espresso?
The espresso community has long established rules about this. Roughly stated, coffee for espresso has to be low in acidity, not too lightly or darkly roasted, heavy bodied, and contain a significant percentage of dry processed beans. But despite everyone’s experience with spectacularly acidic or bitter shots, despite that Pavlovian anticipatory cringe every espresso hound has developed, there is no convincing logical reason for this.
Espresso is more concentrated than regular coffee; so strongly flavored coffees are said to become too strong as espresso shots. But the oils and crema of espresso buffer its extra strength. Moreover, the bad taste of these coffees done as espresso seems less about it being too strong, and more about being unbalanced. The explanation for the unsuitability for espresso of some great brewing coffees may not be in espresso’s strength, its extraction of lipids, or its creation of crema. Rather, it may be that espresso brewing extracts flavors differently, and alters their balance in the little cup. This paper tries to get some answers to what this difference is, how it occurs, and how it can be controlled.
Read the full article here: SOME ASPECTS OF ESPRESSO EXTRACTION
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